Hrmp, I justed started writing a tutorial on using NUnit for XNA projects, but it's far from finished :)
Did you install NUnit using the provided installer (eg. placed the NUnit assemblies in the GAC)?
When you run one of the NUnit TestRunners (either GUI or Console), does it start up properly?
Btw, I can wholeheartedly recommend
TestDriven.NET, it's an addin for Visual Studio (also works in the Express Editions) that will allow you to run your tests directly in VC# Express, optionally even running the test in der Debugger to see what's going wrong if a test fails!
-Markus-
Check out my
website and
blog for some interesting articles and useful utility classes!
Nuclex Framework:
threaded particles,
skinnable GUI,
vector fonts,
texture atlasses and lots more.
WiX XNA Installer: Professional-looking MSI installer template for XNA games.